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- W2019434552 abstract "The γ phase of crystalline phosphine has been studied using IR and Raman spectroscopy. The observations include both pure phases, PH 3 and PD 3 , and many of the modes of PH 3 , PH 2 D and PHD 2 dilute in PD 3 as well as of PD 3 , PD 2 H and PDH 3 dilute in PH 3 . The phase transition β → γ is very slow for PH 3 , but much more rapid for PD 3 . Evidence is adduced pointing to the existence of inequivalent sites in this crystal, but none of a number of suggested models for the unit cell is entirely consistent with the numbers of multiplet components of the internal modes, nor with the numbers of external (lattice) modes observed in the IR and Raman." @default.
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- W2019434552 date "1977-01-01" @default.
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- W2019434552 title "Raman and IR spectra of crystalline phosphine in the γ phase" @default.
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- W2019434552 doi "https://doi.org/10.1016/0022-3697(77)90128-7" @default.
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