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- W2019436630 abstract "Abstract We report a molecular [2]rotaxane which comprises a molecular cage and a dumbbell‐shaped component, in which translational isomerism can be performed reversibly through an in situ anion exchange process, that is, sequential addition of Bu 4 NCl/AgPF 6 reagent pairs. The [2]rotaxane incorporates two pyridinium and two dialkylammonium centers and functions as a triply operable molecular switch, which can be controlled through altering the polarity of the solvent, adding acidic and basic reagents (TFA/Et 3 N), and the varying the nature of the counteranions (Cl − vs PF 6 − )." @default.
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- W2019436630 date "2007-05-04" @default.
- W2019436630 modified "2023-10-18" @default.
- W2019436630 title "Use of Anions To Allow Translational Isomerism of a [2]Rotaxane" @default.
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- W2019436630 doi "https://doi.org/10.1002/chem.200601432" @default.
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