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- W2019439463 abstract "Acylation of (cyclopropylmethyl)trimethylsilane using RCOCl/AlCl 3 (R: saturated hydrocarbon group) constitutes a mild, convenient route to β,γ-unsaturated ketones free from the conjugated isomers. With α,β-unsaturated acyl chlorides a competitive reaction between the C—H and C—Si allylic cleavage is observed whereas chloroacetyl chloride affords the γ,δ-ethylenic corresponding ketone. A mechanism involving the catalytic role of HCl in the formation of β,γ-unsaturated and chloroketones is proposed." @default.
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- W2019439463 date "1981-03-01" @default.
- W2019439463 modified "2023-10-16" @default.
- W2019439463 title "Acylation du (cyclopropylméthyl)triméthylsilane. Une nouvelle voie d'accès aux énones non conjuguées" @default.
- W2019439463 doi "https://doi.org/10.1139/v81-116" @default.
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