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- W2019462069 abstract "Losses of the stabilizer due to extractability or volatility immediately affect the ultimate performance of polymer products. A new approach to increase the persistence of the stabilizer in the final product is to chemically bind it to the polymer backbone. Radiation grafting or crosslinking could be an efficient method for this, when the stabilizer is polymerizable. By a mutual gamma irradiation method photoprotector 2-hydroxy-4-(3-methacryloxy-2-hydroxy-propoxy) benzophenone has been readily grafted to low-density polyethylene in benzene, tetrahydrofuran and methanol solution, respectively. Surface grafting occurs in a methanol solution of stabilizer, while in benzene and tetrahydrofuran solutions of the stabilizer, grafting proceeds more or less in the inner parts of the polymeric film as well. UV stability tests and changes in the mechanical properties of artificially and naturally aged films indicate pronounced protective effect achieved by the grafted stabilizer. Surface grafting is an efficient photostabilization method since the grafted stabilizer is chemically bound to a polymeric surface and in this way the problem of evaporation of blended stabilizers during the prolonged use of polymeric materials is eliminated." @default.
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- W2019462069 date "2004-09-01" @default.
- W2019462069 modified "2023-09-27" @default.
- W2019462069 title "Improvement of the polymer stability by radiation grafting" @default.
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- W2019462069 doi "https://doi.org/10.1016/j.radphyschem.2004.03.045" @default.
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