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• W2019464651 endingPage "4832" @default.
• W2019464651 startingPage "4819" @default.
• W2019464651 abstract "Supramolecular photolyses of 3-chloro-3-phenyl-3H-diazirine (8) were performed within cyclodextrin (CyD) hosts to determine whether these toroidal inclusion compounds could alter the reactivity of the ensuing carbene reaction intermediate, chloro(phenyl)carbene (9). Remarkably, no intramolecular products stemming from carbene 9 could be detected. Instead, modified CyDs were formed via so-called innermolecular reactions. Hence, diazirine 8 was photolyzed in various conventional solvents to gauge the intermolecular reactivity of carbene 9. Relevant results were used to rationalize the CyD innermolecular reaction products." @default.
• W2019464651 created "2016-06-24" @default.
• W2019464651 creator A5002053554 @default.
• W2019464651 creator A5079619663 @default.
• W2019464651 date "2003-05-21" @default.
• W2019464651 modified "2023-10-14" @default.
• W2019464651 title "Inter- and Innermolecular Reactions of Chloro(phenyl)carbene" @default.
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• W2019464651 doi "https://doi.org/10.1021/jo026521h" @default.
• W2019464651 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12790587" @default.
• W2019464651 hasPublicationYear "2003" @default.
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