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- W2019464767 abstract "Abstract The reaction of [Mo7O24][NH4]6 with 3-hydroxypyridine (3-HOPy) and 4-hydroxypyridine (4-HOPy) in water resulted in the crystalline materials of [Mo8O26(3-OPyH)2][3-HOPyH]4 · 4H2O (1) and [Mo8O26(4-OPyH)2][4-HOPyH]4 · 4H2O (2), respectively. Crystal structures of the complexes 1 and 2 reveal that two of the OPyH moieties coordinately linked to two molybdate atoms of Mo8O26 clusters. The crystal structures of 1 and 2 are not iso-structural. However, in both cases the iso-structural Mo8O26(OPyH)2 units join together via N–H⋯O hydrogen bonds to form linear ribbons which are further joined by H2O molecules to form 2D-layers. The cavities or channels of these layers are occupied by the C–H⋯O, O–H⋯O and O–H⋯π aggregates of hydroxypyridinium cations." @default.
- W2019464767 created "2016-06-24" @default.
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- W2019464767 date "2007-01-01" @default.
- W2019464767 modified "2023-10-11" @default.
- W2019464767 title "Hydrogen bonding adducts of octamolybdate anions containing coordinately bound pyridiniumoxides" @default.
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- W2019464767 doi "https://doi.org/10.1016/j.ica.2006.07.041" @default.
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