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- W2019465767 abstract "The conversion of p-nitrotoluene to p-aminobenzaldehyde was found to be most effectively done by a mixture of Na2S4 and ca. two equivalents of NaOH to p-nitrotoluene. After examination of probable intermediates, toluidine, p-nitrobenzaldehyde and p-nitrosotoluene were discarded as the intermediate. The reaction of carbanion ArCO={C}HAr with the sulith the sulfide and the effect of some nitrobenzenes as an electron accepter were examined. These results suggest a mechanism involving a simultaneous oxidation-reduction in a nitrotoluene molecule." @default.
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- W2019465767 date "1979-08-01" @default.
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- W2019465767 title "Mechanism for Reaction of<i>p</i>-Nitrotoluene with Sodium Polysulfide to Form<i>p</i>-Aminobenzaldehyde" @default.
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