Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019466852> ?p ?o ?g. }
- W2019466852 endingPage "4742" @default.
- W2019466852 startingPage "4723" @default.
- W2019466852 abstract "Abstract Kinetically controlled ring‐expansion polymerizations (REPs) are defined syntheses generating cyclic oligomers and polymers without linear intermediates and without equilibration reactions. This review reports syntheses of cyclic metal alkoxides and their use as initiators for REPs of lactones, cyclic diesters, and cyclocarbonates. In addition to homopolyesters, telechelic oligoesters or polyesters, random copolyesters, and A–B–A triblock copolymers can be prepared by these REPs. The in situ combination of REPs with condensation (mostly acylation) reactions allows a broad variation of end groups. The in situ combination of REPs with polycondensation enables various chain‐extension reactions, including the syntheses of multiblock copolymers. With spirocyclic initiators, four‐armed stars with functional end groups may be prepared. The in situ combination of REPs with condensation reactions of trifunctional or multifunctional reagents makes a broad variety of networks accessible. The average segment lengths may be controlled via the monomer/initiator ratios of the REP. All materials produced via the aforementioned REP processes are biodegradable and nontoxic, and this allows for biomedical and pharmaceutical applications. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4723–4742, 2004" @default.
- W2019466852 created "2016-06-24" @default.
- W2019466852 creator A5022047822 @default.
- W2019466852 date "2004-08-17" @default.
- W2019466852 modified "2023-10-17" @default.
- W2019466852 title "Biodegradable polymers with variable architectures via ring-expansion polymerization" @default.
- W2019466852 cites W1484214211 @default.
- W2019466852 cites W1493314366 @default.
- W2019466852 cites W1971933521 @default.
- W2019466852 cites W1972437965 @default.
- W2019466852 cites W1977263116 @default.
- W2019466852 cites W1978250930 @default.
- W2019466852 cites W1979062047 @default.
- W2019466852 cites W1983778067 @default.
- W2019466852 cites W1984464270 @default.
- W2019466852 cites W1993127517 @default.
- W2019466852 cites W1995339715 @default.
- W2019466852 cites W1998440158 @default.
- W2019466852 cites W2001523784 @default.
- W2019466852 cites W2002874745 @default.
- W2019466852 cites W2013382336 @default.
- W2019466852 cites W2016077890 @default.
- W2019466852 cites W2016966033 @default.
- W2019466852 cites W2018319870 @default.
- W2019466852 cites W2018921259 @default.
- W2019466852 cites W2025727608 @default.
- W2019466852 cites W2027954037 @default.
- W2019466852 cites W2032308878 @default.
- W2019466852 cites W2033304731 @default.
- W2019466852 cites W2034604173 @default.
- W2019466852 cites W2035011965 @default.
- W2019466852 cites W2042013361 @default.
- W2019466852 cites W2047367531 @default.
- W2019466852 cites W2052794603 @default.
- W2019466852 cites W2060687896 @default.
- W2019466852 cites W2061954805 @default.
- W2019466852 cites W2062230064 @default.
- W2019466852 cites W2066039033 @default.
- W2019466852 cites W2072561863 @default.
- W2019466852 cites W2078183693 @default.
- W2019466852 cites W2079719602 @default.
- W2019466852 cites W2081995451 @default.
- W2019466852 cites W2082266490 @default.
- W2019466852 cites W2085790227 @default.
- W2019466852 cites W2090862628 @default.
- W2019466852 cites W2118324072 @default.
- W2019466852 cites W2119070388 @default.
- W2019466852 cites W2164287895 @default.
- W2019466852 cites W2167497998 @default.
- W2019466852 cites W2315523904 @default.
- W2019466852 cites W4230542150 @default.
- W2019466852 cites W4239414466 @default.
- W2019466852 doi "https://doi.org/10.1002/pola.20261" @default.
- W2019466852 hasPublicationYear "2004" @default.
- W2019466852 type Work @default.
- W2019466852 sameAs 2019466852 @default.
- W2019466852 citedByCount "93" @default.
- W2019466852 countsByYear W20194668522012 @default.
- W2019466852 countsByYear W20194668522013 @default.
- W2019466852 countsByYear W20194668522014 @default.
- W2019466852 countsByYear W20194668522015 @default.
- W2019466852 countsByYear W20194668522016 @default.
- W2019466852 countsByYear W20194668522017 @default.
- W2019466852 countsByYear W20194668522018 @default.
- W2019466852 countsByYear W20194668522019 @default.
- W2019466852 countsByYear W20194668522020 @default.
- W2019466852 countsByYear W20194668522021 @default.
- W2019466852 countsByYear W20194668522022 @default.
- W2019466852 countsByYear W20194668522023 @default.
- W2019466852 crossrefType "journal-article" @default.
- W2019466852 hasAuthorship W2019466852A5022047822 @default.
- W2019466852 hasConcept C119394753 @default.
- W2019466852 hasConcept C15920480 @default.
- W2019466852 hasConcept C161790260 @default.
- W2019466852 hasConcept C166940927 @default.
- W2019466852 hasConcept C178790620 @default.
- W2019466852 hasConcept C185592680 @default.
- W2019466852 hasConcept C188027245 @default.
- W2019466852 hasConcept C192562407 @default.
- W2019466852 hasConcept C193557335 @default.
- W2019466852 hasConcept C203897987 @default.
- W2019466852 hasConcept C207245611 @default.
- W2019466852 hasConcept C2780378348 @default.
- W2019466852 hasConcept C40875361 @default.
- W2019466852 hasConcept C44228677 @default.
- W2019466852 hasConcept C521977710 @default.
- W2019466852 hasConcept C53033327 @default.
- W2019466852 hasConceptScore W2019466852C119394753 @default.
- W2019466852 hasConceptScore W2019466852C15920480 @default.
- W2019466852 hasConceptScore W2019466852C161790260 @default.
- W2019466852 hasConceptScore W2019466852C166940927 @default.
- W2019466852 hasConceptScore W2019466852C178790620 @default.
- W2019466852 hasConceptScore W2019466852C185592680 @default.
- W2019466852 hasConceptScore W2019466852C188027245 @default.
- W2019466852 hasConceptScore W2019466852C192562407 @default.
- W2019466852 hasConceptScore W2019466852C193557335 @default.
- W2019466852 hasConceptScore W2019466852C203897987 @default.
- W2019466852 hasConceptScore W2019466852C207245611 @default.