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- W2019469650 abstract "The Wannier formula is unable to fit the energy of the lowest level ($n=1$) simultaneously with that of the higher states ($nensuremath{ge}2$) in materials exhibiting a weak dielectric screening. We discuss the theory and the use of the Rydberg formula in condensed matter. We show that it describes all levels ($n=1$ and $nensuremath{ge}2$) and provides values for the energy gaps ${E}_{g}$ and effective Rydbergs ${R}^{s}$ considerably more reliable than those given by the Wannier formula. Furthermore, it clearly shows the close relationship between the excitations of the free atomic or molecular constituents and the excitons in the condensed phases. Solid rare gases are used as a testing example. Applications are made to doped solid rare gases and ${mathrm{H}}_{2}$. A formula for the intensities which generalizes that of the Wannier model is obtained with the same criteria." @default.
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- W2019469650 date "1979-02-15" @default.
- W2019469650 modified "2023-10-16" @default.
- W2019469650 title "Rydberg states in condensed matter" @default.
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- W2019469650 doi "https://doi.org/10.1103/physrevb.19.1683" @default.
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