Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019476906> ?p ?o ?g. }
- W2019476906 endingPage "10992" @default.
- W2019476906 startingPage "10981" @default.
- W2019476906 abstract "Electron transfer (ET) reactions and optical transitions are considered in chromophores with both the dipole moment and the electronic polarizability varying with the transition. An exact solution for reaction free energy surfaces of ET along a reaction coordinate has been obtained in the Drude model for the solute and solvent polarizabilities. The ET surfaces manifest the following effects of a nonzero polarizability variation: they (i) are asymmetric, (ii) have different curvatures at their minima, and (iii) become infinite for reaction coordinates outside a one-sided fluctuation band. The physical origin of these effects is the renormalization of the solute dipole by the solvent reaction field depending on the nonequilibrium solvent configuration. The reorganization energies of ET are substantially different for forward and backward transitions with higher reorganization energy in the state with hider solute polarizability. The dependence of the ET rate on the equilibrium energy gap is quadratic near the rate maximum and is linear at large energy gaps. The energy gap curves are also flatter from the side of exothermic reactions and broader for the state with a higher polarizability. The bandshape analysis of optical transitions is extended to the case of a nonzero polarizability variation." @default.
- W2019476906 created "2016-06-24" @default.
- W2019476906 creator A5003059556 @default.
- W2019476906 creator A5008824308 @default.
- W2019476906 creator A5029827787 @default.
- W2019476906 creator A5088327041 @default.
- W2019476906 date "1999-11-20" @default.
- W2019476906 modified "2023-09-23" @default.
- W2019476906 title "A Theory of Electron Transfer and Steady-State Optical Spectra of Chromophores with Varying Electronic Polarizability" @default.
- W2019476906 cites W1521867405 @default.
- W2019476906 cites W1964542829 @default.
- W2019476906 cites W1964761757 @default.
- W2019476906 cites W1965632157 @default.
- W2019476906 cites W1969073220 @default.
- W2019476906 cites W1969242194 @default.
- W2019476906 cites W1971274408 @default.
- W2019476906 cites W1972489737 @default.
- W2019476906 cites W1973282060 @default.
- W2019476906 cites W1974211472 @default.
- W2019476906 cites W1974276021 @default.
- W2019476906 cites W1975212381 @default.
- W2019476906 cites W1976840537 @default.
- W2019476906 cites W1977880763 @default.
- W2019476906 cites W1979129222 @default.
- W2019476906 cites W1980169574 @default.
- W2019476906 cites W1980428065 @default.
- W2019476906 cites W1981231666 @default.
- W2019476906 cites W1981520015 @default.
- W2019476906 cites W1983544390 @default.
- W2019476906 cites W1984826388 @default.
- W2019476906 cites W1988297638 @default.
- W2019476906 cites W1989081160 @default.
- W2019476906 cites W1991028562 @default.
- W2019476906 cites W1992021800 @default.
- W2019476906 cites W1993077149 @default.
- W2019476906 cites W1995842593 @default.
- W2019476906 cites W1998533858 @default.
- W2019476906 cites W2000364980 @default.
- W2019476906 cites W2003657760 @default.
- W2019476906 cites W2005082688 @default.
- W2019476906 cites W2010643843 @default.
- W2019476906 cites W2011245107 @default.
- W2019476906 cites W2011354812 @default.
- W2019476906 cites W2011818093 @default.
- W2019476906 cites W2012116438 @default.
- W2019476906 cites W2012366461 @default.
- W2019476906 cites W2012403484 @default.
- W2019476906 cites W2021308443 @default.
- W2019476906 cites W2022205840 @default.
- W2019476906 cites W2023242573 @default.
- W2019476906 cites W2024067522 @default.
- W2019476906 cites W2025823762 @default.
- W2019476906 cites W2028761393 @default.
- W2019476906 cites W2031005754 @default.
- W2019476906 cites W2031904472 @default.
- W2019476906 cites W2032341384 @default.
- W2019476906 cites W2034752870 @default.
- W2019476906 cites W2035338940 @default.
- W2019476906 cites W2036264937 @default.
- W2019476906 cites W2036791731 @default.
- W2019476906 cites W2038943405 @default.
- W2019476906 cites W2041632771 @default.
- W2019476906 cites W2044643907 @default.
- W2019476906 cites W2046133238 @default.
- W2019476906 cites W2046561747 @default.
- W2019476906 cites W2047892543 @default.
- W2019476906 cites W2050155948 @default.
- W2019476906 cites W2050538682 @default.
- W2019476906 cites W2056288284 @default.
- W2019476906 cites W2057270145 @default.
- W2019476906 cites W2057892711 @default.
- W2019476906 cites W2059282210 @default.
- W2019476906 cites W2059589059 @default.
- W2019476906 cites W2061123442 @default.
- W2019476906 cites W2062851494 @default.
- W2019476906 cites W2063753067 @default.
- W2019476906 cites W2063980911 @default.
- W2019476906 cites W2065735602 @default.
- W2019476906 cites W2067284685 @default.
- W2019476906 cites W2071031838 @default.
- W2019476906 cites W2072473403 @default.
- W2019476906 cites W2073543532 @default.
- W2019476906 cites W2074143169 @default.
- W2019476906 cites W2074768610 @default.
- W2019476906 cites W2078178969 @default.
- W2019476906 cites W2078877853 @default.
- W2019476906 cites W2081137209 @default.
- W2019476906 cites W2086279922 @default.
- W2019476906 cites W2088044183 @default.
- W2019476906 cites W2089707780 @default.
- W2019476906 cites W2089933609 @default.
- W2019476906 cites W2091237955 @default.
- W2019476906 cites W2095210885 @default.
- W2019476906 cites W2095480015 @default.
- W2019476906 cites W2113274671 @default.
- W2019476906 cites W2120313431 @default.
- W2019476906 cites W2145644650 @default.
- W2019476906 cites W2151738089 @default.