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• W2019480149 abstract "We present a theoretical analysis of the phase behavior of colloid-polymer mixtures which applies to all polymer/colloid size ratios $q$. It accounts for the crossover from a constant length scale $R$ (radius of gyration) in the colloid limit (small $q$) to the concentration-dependent correlation length $ensuremath{xi}$ in the protein limit $(q>1)$. We obtain predictions that fully agree with observations and simulations. In the protein limit the colloid concentrations $ensuremath{eta}$ along the binodals become independent of $q$ and the polymer concentrations $ensuremath{varphi}$ scale as ${q}^{1∕ensuremath{gamma}}$, where $ensuremath{gamma}=0.77$ is the scaling exponent in $ensuremath{xi}ensuremath{sim}{ensuremath{varphi}}^{ensuremath{-}ensuremath{gamma}}$: phase diagrams plotted as $ensuremath{varphi}{q}^{ensuremath{-}1∕ensuremath{gamma}}$ vs $ensuremath{eta}$ are then independent of $q$. The liquid window in the protein limit is narrow." @default.
• W2019480149 created "2016-06-24" @default.
• W2019480149 creator A5047129609 @default.
• W2019480149 creator A5088753801 @default.
• W2019480149 date "2007-10-09" @default.
• W2019480149 modified "2023-09-24" @default.
• W2019480149 title "Analytical phase diagram for colloid-polymer mixtures" @default.
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• W2019480149 doi "https://doi.org/10.1103/physreve.76.041802" @default.
• W2019480149 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17995014" @default.
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