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- W2019483516 abstract "Abstract Perfluoroalkyl side-chain polyesters with aliphatic hydrocarbon backbone spacers of different chain lengths have been synthesized in high yield directly from the hydrocarbon diacid and perfluoroalkyl 3,5-dihydroxybenzoate. Molecular weights up to 22 000 Mn were obtained. The linear mesogenic perfluoroalkyl segment lengths -(CF2)n- were varied, polyesters with n= 10 and 7 showing crystalline and liquid crystalline phases, while with n = 6 mainly amorphous polyesters were obtained. The mesophases were investigated by polarizing optical microscopy, DSC and X-ray diffraction. They have a grainy optical texture in the POM and give multiple transitions on DSC. In these polymers both the nature of the mesogenic group and the dilution of the mesogenic side-chains along the polymer backbone can be varied." @default.
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- W2019483516 date "1995-02-01" @default.
- W2019483516 modified "2023-09-27" @default.
- W2019483516 title "Preliminary Communication Novel fluorocarbon side-chain polyesters based on 3,5-dihydroxybenzoic acid" @default.
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- W2019483516 doi "https://doi.org/10.1080/02678299508036631" @default.
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