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• W2019496847 abstract "Abstract Watson's treatment of the theory of centrifugal distortion effects is reviewed in detail and special attention is drawn to the relationship between Watson's treatment and the Kivelson-Wilson treatment. The relationship between the distortion parameters and the force field for XYZ-type molecules is also reviewed in order to remove ambiguities and inconsistencies presently found in the literature. Finally, procedures for exploiting the statistics associated with a least-squares analysis of the data are presented as a guide for model testing and for detecting misassignments and mismeasurements. A series of examples illustrating the results of these procedures are presented using the published spectra of SO 2 , OF 2 , SiF 2 and NSF. In the cases of OF 2 , SiF 2 and NSF, improved values for the rotational constants are obtained." @default.
• W2019496847 created "2016-06-24" @default.
• W2019496847 creator A5076090974 @default.
• W2019496847 date "1972-02-01" @default.
• W2019496847 modified "2023-09-26" @default.
• W2019496847 title "On the calculation and interpretation of centrifugal distortion constants: A statistical basis for model testing: The calculation of the force field" @default.
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• W2019496847 doi "https://doi.org/10.1016/0022-2852(72)90210-x" @default.
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