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- W2019501612 abstract "(Silyl)methyl-silyl-ather 9a–e wurden synthetisiert mit dem Ziel, eine theoretisch mogliche thermische dyotrope Valenzisomerisierung zu beobachten, bei der die Silylgruppen ihre Platze vertauschen. Die Thermolyse fuhrt tatsachlich zu der gewunschten Umlagerung, wobei sich ein Gleichgewicht einstellt. Die Aktivierungsparameter Ea ≈ 32 kcal/mol bzw. ΔS≠ ≈ −9 Clausius werden im Rahmen eines konzertierten Umlagerungsmechanismus diskutiert.Dyotropic Rearrangements, VII: Synthesis and Thermal Rearrangement of (Silyl)methyl silyl Ethers.(Silyl)methyl silyl ethers 9a–e were synthesized in order to observe a theoretically possible thermal dyotropic valence isomerization, in which the silyl groups interchange their positions. Thermolysis does indeed lead to the desired rearrangement, Whereby an equilibrium is established. The activation parameters of Ea ≈ 32 kcal/mol and ΔS≠ ≈ −9 e. u. are discussed within the framework of a concerted rearrangement mechanism." @default.
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- W2019501612 title "Dyotrope Umlagerungen, VII: Synthese und thermische Umlagerung von (Silyl) methyl-silyl-äthern" @default.
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- W2019501612 doi "https://doi.org/10.1002/cber.19761090808" @default.
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