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- W2019528512 abstract "Rate constants k q T ranging between 0.3×10 9 and 15×10 9 M -1 s -1 for quenching of the lowest excited triplet state of several substituted aromatic hydrocarbons and ketones by molecular oxygen were measured in toluene. The efficiencies of singlet oxygen (O 2 ( 1 Δg)) formation S Δ were determined, ranging from 0.24 to 1.00. The results can be explained by CT interaction in that k q T and S Δ correlate with the free enthalpy of electron transfer ΔG el , calculated from the redox potentials of the sensitizer and O 2" @default.
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- W2019528512 date "1994-04-01" @default.
- W2019528512 modified "2023-09-30" @default.
- W2019528512 title "Mechanism of the Triplet-State Quenching by Molecular Oxygen in Solution" @default.
- W2019528512 doi "https://doi.org/10.1021/j100067a006" @default.
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