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- W2019553629 abstract "The Wolff–Kishner reaction converts 1,5-anhydro-4,6-O-benzylidene-2-deoxy-D-erythro-hex-3-ulose (1) into its 3-deoxygenated analogue (2) in high yield. In contrast, methyl 4,6-O-benzylidene-3-deoxy-β-D-erythro-hexopyranosid-2-ulose (3) and methyl 4,6-O-benzylidene-2-deoxy-α-D-erythro-hexopyranosid-3-ulose (10) afford complex mixtures of products, most of which appear to arise through elimination processes; the expected deoxygenated glycosides (5) and (11) were isolated in only moderate and low yields, respectively. A slightly modified procedure in the reaction with (10) provided the pyrazole derivative (14) as the only product in high yield." @default.
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- W2019553629 date "1977-01-01" @default.
- W2019553629 modified "2023-10-03" @default.
- W2019553629 title "Deoxygenation of sugar derivatives by the Wolff–Kishner reaction" @default.
- W2019553629 doi "https://doi.org/10.1039/p19770001564" @default.
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