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- W2019554809 abstract "Multication compounds are considered to have interesting applications. Among the variety of possible AmBnXp materials, however, the research work has been unevenly distributed, as the ABX2 chalcopyrites have attracted the majority of the efforts. The related family of AB2X4 defect chalcopyrites, which is characterized by an ordered sublattice of vacancies and then by a further degree of freedom as to tailoring possibilities, has on the other hand received much less attention. Here we discuss the results obtained in the crystal growth and in the structural and dynamical (Raman) analysis of about sixty different ternary and pseudoternary AB2X4 compounds or phases. The reaction products can be grouped in three different structural families: cubic-spinel AB2X4 structures (CdIn2S4 like), AB2OX4 layered hexagonal structures (ZnIn2S4 like) and AB2□X4 defective tetragonal structures (CdGa2S4 like). Our attention has been primarily devoted to the defective phases, which have been obtained in the great majority of the starting compositions studied." @default.
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- W2019554809 date "1984-07-01" @default.
- W2019554809 modified "2023-09-27" @default.
- W2019554809 title "Ternary and pseudoternary AB2X4 compounds (A = Zn, Cd; B = Ga, In; X = S, Se)" @default.
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- W2019554809 doi "https://doi.org/10.1016/0254-0584(84)90088-9" @default.
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