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- W2019563129 abstract "A multifunctional macroinitiator for single-electron-transfer mediated living radical polymerization (SET-LRP) was designed from acetylated galactoglucomannan (AcGGM) by α-bromoisobutyric acid functionalization of the anomeric hydroxyl groups on the heteropolysaccharide backbone. This macroinitiator, with a degree of substitution of 0.15, was used in the SET-LRP of methyl acrylate, catalyzed by Cu0/Me6-TREN in DMSO, DMF, or DMSO/H2O in various concentrations. Kinetic analyses confirm high conversions of up to 99.98% and a living behavior of the SET-LRP process providing high molecular weight hemicelluloses/methyl acrylate hybrid copolymers with a brush-like architecture." @default.
- W2019563129 created "2016-06-24" @default.
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- W2019563129 date "2010-12-17" @default.
- W2019563129 modified "2023-10-03" @default.
- W2019563129 title "Hemicellulose-Based Multifunctional Macroinitiator for Single-Electron-Transfer Mediated Living Radical Polymerization" @default.
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- W2019563129 doi "https://doi.org/10.1021/bm101357k" @default.
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