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- W2019566231 abstract "GIBBS1, in his discussion of the phase rule, arrives at certain relations among the pressure, temperature and chemical potentials for two-component two-phase systems, making use of a fundamental equation now commonly known as the Gibbs–Duhem relation. A detailed account of this work has been given by Butler2. Since these systems have two degrees of freedom, the derivatives involving the intensive variables are of the form (∂x/∂y)z. By introducing second-order Jacobians, the properties of the systems in question can be summarized compactly, and the results given by Gibbs and Butler readily obtained. The first systematic application of Jacobians to thermodynamical systems was made by Shaw3. The chief property required here is that: where β and γ being any two admissible variables." @default.
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- W2019566231 date "1960-04-01" @default.
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- W2019566231 title "Thermodynamical Relations in Two-Component Two-Phase Systems" @default.
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- W2019566231 doi "https://doi.org/10.1038/186299a0" @default.
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