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- W2019589456 abstract "Lanthanide based dyes belong to one of the most promising fields of photovoltaic research,combining high quantum yields and large spectral shift. However, many challenges are faced whenworking with lanthanide dyes for spectral conversion: their thermal and chemical stability, whichcan greatly influence the shelf-life of the dyes; the absorption band position, which depends on theorganic part of the dye, the so called antenna; self-quenching mechanisms, which lead to aphotoluminescence emission loss. The chemical composition of the surrounding environment of thedyes has a fundamental role in their properties. In this paper, the optical and PLQY(photoluminescence quantum yield) properties of an europium-based dye embedded in a silicamatrix are reported. The in-house synthesized dye consists of a bis(2-(diphenylphosphino)phenyl)ether oxide (DPEPO) ligand and three hexafluoroacetylacetonate (hfac)co-ligands coordinating a central europium ion. The dye has been included in porous core-shellparticles, to study its optical properties once embedded in a solid dielectric matrix. The opticalproperties of the resulting samples have been characterized by photoluminescence emission andPLQY measurements. The results have been compared with data obtained from a commerciallyavailable dye (BASF Lumogen family) in similar conditions." @default.
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- W2019589456 date "2012-06-01" @default.
- W2019589456 modified "2023-10-18" @default.
- W2019589456 title "Optical properties of lanthanide dyes for spectral conversion encapsulated in porous silica nanoparticles" @default.
- W2019589456 doi "https://doi.org/10.1117/12.922591" @default.
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