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• W2019605110 endingPage "781" @default.
• W2019605110 startingPage "778" @default.
• W2019605110 abstract "The formation, stereostructure, and cellular reactions of the 7,8-diol-9,10-epoxide metabolites of the carcinogen benzo[a]pyrene have been examined after topical application of benzo[a]pyrene to the skin of mice. In this known target tissue, polymer adducts from diastereomeric diol epoxides, (+)-(7S, 8R, 9R, 10R) and (+)-(7R, 8S, 9R, 10R), were formed stereospecifically from their corresponding 7,8-dihydrodiols. Both diol epoxides bind with proteins, RNA, and DNA in vivo. For the nucleic acids, binding occurs preferentially at the 2-amino group of guanine in cellular RNA and DNA in vivo. Methods for establishing the structure of the cellular adducts as well as the possible biological implications of their formation are discussed." @default.
• W2019605110 created "2016-06-24" @default.
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• W2019605110 date "1978-02-17" @default.
• W2019605110 modified "2023-10-16" @default.
• W2019605110 title "Binding of Nenzo[ <i>a</i> ]pyrene 7,8-Diol-9,10-Epoxides to DNA, RNA, and Protein of Mouse Skin Occurs with High Stereoselectivity" @default.
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• W2019605110 doi "https://doi.org/10.1126/science.622566" @default.
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