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- W2019607383 abstract "The temperature dependence of the TO and LO phonon frequencies and of the coupled plasmon-LO phonon modes was determined from the FIR reflection spectra of the skutterudites CoAs3 and CoSb3 and of some skutterudite type mixed crystals in the frequency range 30–700 cm−1 from 80 to 700 K. A strongly temperature-dependent plasma frequency of free carriers is found in CoAs3. No free-carrier contribution to the FIR reflectivitity, however, was observed in the case of CoSb3. From the FIR spectra of cationic (Co1−xFexSb3, Co1−xNixSb3, Co1−2xFexNixSb3) and anionic (CoAs3−xPx) substituted mixed crystals an anionic defect structure is proposed to be responsible for the free-carrier contributions in CoAs3." @default.
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- W2019607383 modified "2023-09-25" @default.
- W2019607383 title "Temperature dependence of the FIR reflection spectra of the skutterudites CoAs3 and CoSb3" @default.
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- W2019607383 doi "https://doi.org/10.1016/0020-0891(84)90066-6" @default.
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