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- W2019618492 abstract "Abstract The corrosion of a metal dissolving stepwise with formation of low-valency intermediates and Mn+ ion as the final corrosion product proceeds by a complex electrochemical-chemical mechanism comprising following steps: M → M+ + e; M+ → Mn+ + (n − 1)Ox → Mn + )n − 1)O−x and Ox + e → O−x. A criterion of such a corrosion mechanism is the deviation of the experimental corrosion rate (ic) from the reduction rate of oxidant Ox at the corrosion potential (iextr.c) found by extrapolation. Cathodic polarization curves on indium have been measured and its corrosion rate has been determined by a radiotracer method in aqueous NaClO4 + HClO4 solutions of varying acidity. ic is considerably higher than iextr., the ratio ic/iextr.c approaching 3 with increasing acidity. In the same solutions containing O·M NaCl ic = iextr.c independent of acidity." @default.
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- W2019618492 date "1973-08-01" @default.
- W2019618492 modified "2023-09-25" @default.
- W2019618492 title "Corrosion of stepwise dissolving metals; corrosion mechanism of indium" @default.
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- W2019618492 doi "https://doi.org/10.1016/0013-4686(73)85024-8" @default.
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