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- W2019632012 abstract "We have investigated the scope and mechanism of the “three-component” synthesis of substituted CpRe(CO)3 complexes which involves the reaction of nucleophiles with diazocyclopentadiene (C5H4N2) and a fac-Re(CO)3+ species. We found that only moderately strong nucleophiles (halogen, carboxylates, boronic acids) are suitable for this transformation and that it shows a great sensitivity to the steric and electronic features of the nucleophile. A Hammett-type ρσ analysis of the effect of para-substituents on the relative rate of this reaction with several benzoates showed that the reaction is accelerated by electron-donating substituents. A mechanistic analysis, based on structure/reactivity relationships and NMR experiments, indicated that the nucleophile initially reacts with the rhenium precursor. Then, in the rate-determining step, the resulting preassociated rhenium−nucleophile intermediate reacts with C5H4N2 via a concerted SN2-like transition state. The same general mechanistic pathway seems to be followed by two very different classes of nucleophiles, carboxylates and boronic acids, in the synthesis of acyloxy- and carbon-substituted CpRe(CO)3 complexes, respectively. In particular, the lack of reactivity of boronic esters can be explained by the necessary preassociation step between the rhenium and a deprotonated hydroxy group of the nucleophile, which is possible only with free boronic acids." @default.
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- W2019632012 title "Three-Component Synthesis of Substituted η<sup>5</sup>-Cyclopentadienyltricarbonylrhenium Complexes: Scope, Limitations, and Mechanistic Interpretations" @default.
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- W2019632012 doi "https://doi.org/10.1021/om990128t" @default.
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