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- W2019642023 abstract "Abstract Three homodinuclear lanthanide complexes [ Ln 2 (μ‐L) 3 ] [ Ln = La ( 1 ), Nd ( 2 ), Sm ( 3 )] were synthesized by the reaction of Ln [N(SiMe 3 ) 2 ] 3 ( Ln = La, Nd, Sm) with 1.5 equiv. of the salen‐type ligand N , N ‐bis(3, 5‐di‐ tert ‐butyl‐salicylidene)‐1, 3‐diaminobenzene (H 2 L) in THF at room temperature. X‐ray diffraction studies revealed that the coordination arrangement around each lanthanide atom could be best described as distorted octahedral for complexes 2 and 3 and the two lanthanide metal ions are linked together by the three rigid m ‐phenylenediamine‐based ligands. The ring‐opening polymerization (ROP) of ϵ‐caprolactone (ϵ‐CL) was carried out using the complexes 1 – 3 as catalysts. The catalytic activities of dinuclear lanthanide complexes were greatly affected by ionic radii and the increased active order is Sm < Nd < La." @default.
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- W2019642023 date "2012-05-31" @default.
- W2019642023 modified "2023-09-24" @default.
- W2019642023 title "Synthesis, Structure, and Reactivity of Homodinuclear Lanthanide Complexes Bearing Salen-type Schiff-base Ligand" @default.
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- W2019642023 doi "https://doi.org/10.1002/zaac.201200046" @default.
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