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- W2019653401 abstract "Blum's generalized inverse screening length parameter Γ is solved numerically for 1:1 type of fused salts. Using these Γ parameters for the salts, a method is evolved for the evaluation of the entropies of fused salts by treating the different components of the salts as seperate mass entities along with the concept that the total entropy is a sum of the contributions from neutral hardspheres and that due to charging process. The entropies so calculated are found to be in good agreement with experiment. Further from the parameters Γ, the excess thermodynamic properties and the contact values of the partial radial distribution functions are calculated. A simple method is given in the evaluation of the parameter Γ which is found to yield almost similar values as that given by Blum. Der verallgemeinerte inverse Abschirmlängenparameter Γ nach Blum wird numerisch für ein geschmolzenes 1:1-Salz gelöst. Mit diesem Γ-Parameter für die Salze wird eine Methode zur Berechnung der Entropien der geschmolzenen Salze durch Behandlung der verschieden en Komponenten der Salze als getrennte Mengeneinheiten zusammen mit der Vorstellung, daß die Gesamt-Entropie eine Summe der Beiträge von neutralen harten Kugeln und denen der Ladungsprozesse darstellt, entwickelt. Die so berechneten Entropien befinden sich in guter Übereinstimmung mit dem Experiment. Ferner werden aus den Parametern Γ die thermodynamischen Überschußeigenschaften und die Kontaktwerte der partiellen radialen Verteilungsfunktionen berechnet. Die einfache Methode zur Berechnung der Γ-Parameter wird angegeben, die fast ähnliche Werte wie die von Blum liefert." @default.
- W2019653401 created "2016-06-24" @default.
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- W2019653401 date "1988-11-01" @default.
- W2019653401 modified "2023-09-27" @default.
- W2019653401 title "On the Evaluation of Entropy and Thermodynamic Properties of 1:1 Type of Molten Salts through the Generalized Debye Inverse Screening Length" @default.
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- W2019653401 doi "https://doi.org/10.1002/pssb.2221500108" @default.
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