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• W2019658135 abstract "The molecular structure of magnesium bis-acetylacetonate has been determined by synchronous gas-phase electron diffraction (GED) and mass spectrometric experiment and quantum mechanical calculations (HF/6-311+G(d,p), B3LYP/6-311+G(d,p), and MP2/6-311+G(d,p)). Both experimental and theoretical approaches yielded the structure of D2d symmetry with chelate rings located in perpendicular planes. Major structural parameters determined by GED experiment are the following: bond distances rα(Mg–O)=1.966(4), rα(O–C)=1.279(2), rα(C–C′)=1.408(3), rα(C–Cm)=1.534(4) Å; valence angles ∠α(O–Mg–O)=93.3(2), ∠α(O–C′–C)=125.3(2), ∠α(O–C–Cm)=116.2(4)°." @default.
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• W2019658135 date "2004-09-01" @default.
• W2019658135 modified "2023-10-14" @default.
• W2019658135 title "The molecular structure of Mg(acac)2 determined by gas-phase electron diffraction and quantum mechanical calculations" @default.
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• W2019658135 doi "https://doi.org/10.1016/j.molstruc.2004.05.019" @default.
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