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• W2019664554 startingPage "1490" @default.
• W2019664554 abstract "A new polymeric ligand, 6-(3,4-dicyanophenylthio)-hexyl-2-polytetrahydrofuranacetate (2) and its liquid crystalline polymeric phthalocyanine, 2,9,16,23-tetrakis-{6-(polytetrahydrofuran-2-carboxylate)-hexylthio-phthalocyaninatocobalt(II) (3), {Co[Pc(S-C6H13OCO-poly-THF)4]}(CoPcLC) have been synthesized. The ligand and the phthalocyanine, bearing polytetrahydrofuran moieties (poly-THF), were characterized using elemental analysis, FTIR, 1H and 13C NMR, and UV–Vis techniques. CoPcLC (3) promotes a greater interaction between the mesogens, resulting in solution aggregations together with a red-shift in the Q-band in the presence of the soft Ag+ ion. The dielectric anisotropy and phase transition temperature values of CoPcLC doped with 4-cyano-4′-n-pentylbiphenyl (5CB) were found to be 7.17 and 40.5 °C, respectively. The dielectrical anisotropy behaviour of the liquid crystals changes from the positive to the negative type. The current–voltage characteristics of the liquid crystals show a non-linear behaviour." @default.
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• W2019664554 date "2009-06-01" @default.
• W2019664554 modified "2023-09-24" @default.
• W2019664554 title "Synthesis and liquid crystal properties of phthalocyanine bearing a star polytetrahydrofuran moiety" @default.
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• W2019664554 doi "https://doi.org/10.1016/j.poly.2009.02.038" @default.
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