FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019664562> ?p ?o ?g. }

• W2019664562 endingPage "2813" @default.
• W2019664562 startingPage "2804" @default.
• W2019664562 abstract "As part of a study on the oxidation mechanism of heterocyclic aromatic compounds, some aspects of the atmospheric chemistry of several alkyl derivatives of furan have been investigated. The aim of this work was to identify the products of the reactions of chlorine atoms with 2-methylfuran, 2-ethylfuran and 2,5-dimethylfuran. Experiments were performed in two different smog chambers at 296 ± 2 K and 1000 ± 20 mbar of synthetic air. The experimental investigation was carried out using in situ long-path FTIR absorption spectroscopy and both SPME-GC/FID-ECD and SPME-GC/MS as sampling and detection techniques. The major primary products from the addition reaction channel were 4-oxo-2-pentenoyl chloride and formaldehyde for the reactions of 2-methylfuran and 2,5-dimethylfuran; 4-oxo-2-hexenoyl chloride and acetaldehyde for the reaction of 2-ethylfuran and 5-chloro-2(5H)-furanone for the reactions of both 2-methylfuran and 2-ethylfuran. Other minor products were 4-oxo-2-pentenal, 4-oxo-2-hexenal and 3-hexene-2,5-dione for the 2-methylfuran, 2-ethylfuran and 2,5-dimethylfuran reactions, respectively. From the abstraction pathway, HCl, furfural, 2-acetylfuran, 5-methylfurfural, maleic anhydride and 5-hydroxy-2(5H)-furanone were detected. The formation of furfural, 2-acetylfuran and 5-methylfurfural confirmed the H-atom abstraction from the alkyl group of 2-methylfuran, 2-ethylfuran and 2,5-dimethylfuran, respectively. This mechanism was not observed in previous studies with OH and NO3 radicals. A mechanism is proposed to explain the main reaction products observed. The observed products confirm that addition of Cl atoms to the double bond of the alkylfuran is the dominant reaction pathway." @default.
• W2019664562 created "2016-06-24" @default.
• W2019664562 creator A5008075040 @default.
• W2019664562 creator A5036446195 @default.
• W2019664562 creator A5045989576 @default.
• W2019664562 creator A5060026711 @default.
• W2019664562 creator A5066178487 @default.
• W2019664562 creator A5088777631 @default.
• W2019664562 date "2009-06-01" @default.
• W2019664562 modified "2023-10-17" @default.
• W2019664562 title "Atmospheric degradation of alkylfurans with chlorine atoms: Product and mechanistic study" @default.
• W2019664562 cites W1965438702 @default.
• W2019664562 cites W1980141544 @default.
• W2019664562 cites W1981291647 @default.
• W2019664562 cites W1988190202 @default.
• W2019664562 cites W1994831894 @default.
• W2019664562 cites W1999934305 @default.
• W2019664562 cites W2013260855 @default.
• W2019664562 cites W2013587390 @default.
• W2019664562 cites W2018057211 @default.
• W2019664562 cites W2021281637 @default.
• W2019664562 cites W2026566059 @default.
• W2019664562 cites W2029873666 @default.
• W2019664562 cites W2030601441 @default.
• W2019664562 cites W2044499383 @default.
• W2019664562 cites W2044641225 @default.
• W2019664562 cites W2056307933 @default.
• W2019664562 cites W2064384524 @default.
• W2019664562 cites W2071706389 @default.
• W2019664562 cites W2071799644 @default.
• W2019664562 cites W2071817017 @default.
• W2019664562 cites W2074558876 @default.
• W2019664562 cites W2080703104 @default.
• W2019664562 cites W2089533587 @default.
• W2019664562 cites W2093772610 @default.
• W2019664562 cites W2094879263 @default.
• W2019664562 cites W2111155943 @default.
• W2019664562 cites W2120075878 @default.
• W2019664562 cites W2124904730 @default.
• W2019664562 cites W2129490531 @default.
• W2019664562 cites W2148308698 @default.
• W2019664562 cites W2321145725 @default.
• W2019664562 cites W2324621407 @default.
• W2019664562 cites W4256033450 @default.
• W2019664562 doi "https://doi.org/10.1016/j.atmosenv.2009.02.030" @default.
• W2019664562 hasPublicationYear "2009" @default.
• W2019664562 type Work @default.
• W2019664562 sameAs 2019664562 @default.
• W2019664562 citedByCount "26" @default.
• W2019664562 countsByYear W20196645622012 @default.
• W2019664562 countsByYear W20196645622013 @default.
• W2019664562 countsByYear W20196645622014 @default.
• W2019664562 countsByYear W20196645622015 @default.
• W2019664562 countsByYear W20196645622017 @default.
• W2019664562 countsByYear W20196645622018 @default.
• W2019664562 countsByYear W20196645622019 @default.
• W2019664562 countsByYear W20196645622020 @default.
• W2019664562 countsByYear W20196645622021 @default.
• W2019664562 countsByYear W20196645622022 @default.
• W2019664562 countsByYear W20196645622023 @default.
• W2019664562 crossrefType "journal-article" @default.
• W2019664562 hasAuthorship W2019664562A5008075040 @default.
• W2019664562 hasAuthorship W2019664562A5036446195 @default.
• W2019664562 hasAuthorship W2019664562A5045989576 @default.
• W2019664562 hasAuthorship W2019664562A5060026711 @default.
• W2019664562 hasAuthorship W2019664562A5066178487 @default.
• W2019664562 hasAuthorship W2019664562A5088777631 @default.
• W2019664562 hasConcept C139066938 @default.
• W2019664562 hasConcept C161790260 @default.
• W2019664562 hasConcept C178790620 @default.
• W2019664562 hasConcept C185592680 @default.
• W2019664562 hasConcept C2775930285 @default.
• W2019664562 hasConcept C2777595113 @default.
• W2019664562 hasConcept C2778517439 @default.
• W2019664562 hasConcept C2778659115 @default.
• W2019664562 hasConcept C2778695967 @default.
• W2019664562 hasConcept C2779719330 @default.
• W2019664562 hasConcept C2780161600 @default.
• W2019664562 hasConcept C2780263894 @default.
• W2019664562 hasConcept C505241676 @default.
• W2019664562 hasConcept C65024703 @default.
• W2019664562 hasConcept C75473681 @default.
• W2019664562 hasConceptScore W2019664562C139066938 @default.
• W2019664562 hasConceptScore W2019664562C161790260 @default.
• W2019664562 hasConceptScore W2019664562C178790620 @default.
• W2019664562 hasConceptScore W2019664562C185592680 @default.
• W2019664562 hasConceptScore W2019664562C2775930285 @default.
• W2019664562 hasConceptScore W2019664562C2777595113 @default.
• W2019664562 hasConceptScore W2019664562C2778517439 @default.
• W2019664562 hasConceptScore W2019664562C2778659115 @default.
• W2019664562 hasConceptScore W2019664562C2778695967 @default.
• W2019664562 hasConceptScore W2019664562C2779719330 @default.
• W2019664562 hasConceptScore W2019664562C2780161600 @default.
• W2019664562 hasConceptScore W2019664562C2780263894 @default.
• W2019664562 hasConceptScore W2019664562C505241676 @default.
• W2019664562 hasConceptScore W2019664562C65024703 @default.
• W2019664562 hasConceptScore W2019664562C75473681 @default.
• W2019664562 hasIssue "17" @default.

• next