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- W2019684103 abstract "Stability constants and entropies and enthalpies of formation of platinum(II)–olefin complexes of the type (CH2:CH·[CH2]n·LR2R′)+PtCl3–(L = N, P, and As; n= 1 and 2) have been obtained in aqueous solution, by a spectrophotometric method. It is shown that these olefins have affinities for platinum(II) comparable with those of the heavier halide ions. Analysis of the enthalpy and entropy changes indicates that the π-acceptor capacity of the olefin is more important than its σ-donor capacity for the formation of stable platinum–olefin bonds." @default.
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- W2019684103 date "1967-01-01" @default.
- W2019684103 modified "2023-09-25" @default.
- W2019684103 title "Platinum complexes with unsaturated amines. Part III. The thermodynamics of formation of complexes (CH<sub>2</sub>:CH·[CH<sub>2</sub>]<sub>n</sub>·LR<sub>2</sub>R′)<sup>+</sup>PtCl<sub>3</sub><sup>–</sup>(L = N, P, and As; n= 1 and 2)" @default.
- W2019684103 doi "https://doi.org/10.1039/j19670000324" @default.
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