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- W2019687509 abstract "Abstract In the first part of this investigation it was shown that, using strictly constant methods of preparation of the sample, reproducibility and precision of kinetic Fourier transform-infrared measurements are sufficient to obtain quantitative values for velocity constants for HD exchange reactions of surface OH groups in the system Pt Al 2 O 3 . The exchange reactions show a fast and a slow partial reaction, the relative abundance of which depends on the initial coverage of the oxide with OH or OD. Model calculations are based on the assumption that those hydroxyls which exchange in a fast reaction are those which are connected with a Pt crystallite via adjacent hydroxyl groups." @default.
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- W2019687509 date "1986-08-01" @default.
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- W2019687509 title "Hydrogen spillover and H$z.sbnd;D exchange in the system Pt/Al2O3II. Experimental problems and influence of OH- or OD-coverage" @default.
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- W2019687509 doi "https://doi.org/10.1016/0021-9517(86)90104-1" @default.
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