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• W2019703057 abstract "Reacting 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide [{PhP(Se)(μ-Se)}2], Woollins’ reagent, with an equivalent of aromatic diol in refluxing toluene afforded 10-membered phosphorus–selenium heterocycles 1 and 2 with an O–P(Se)–Se–Se–P(Se)–O linkage. Two equivalents of aromatic diol and Woollins’ reagent in refluxing toluene gave seven-membered phosphorus–selenium heterocycles 3 and 4 with an O–P(Se)–O linkage together with 10-membered phosphorus–selenium heterocycles 1 and 2. It was also found that the diphosphorus species O–P(Se)–Se–Se–P(Se)–O rings 1 and 2 could be readily ring contracted into the monophosphorus rings 3 and 4 in almost quantitative yields via further reaction with another equivalent of corresponding aromatic diol. One representative X-ray structure is reported." @default.
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• W2019703057 date "2011-03-01" @default.
• W2019703057 modified "2023-09-27" @default.
• W2019703057 title "Formation of new organoselenium heterocycles and ring reduction of 10-membered heterocycles into seven-membered heterocycles" @default.
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• W2019703057 doi "https://doi.org/10.1016/j.poly.2010.12.018" @default.
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