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- W2019717364 abstract "In several experimental studies of electron paramagnetic resonance and antiferromagnetic resonance performed on the one-dimensional Heisenberg antiferromagnet KCuF 3 , a Dzyaloshinsky-Moriya (DM) antisymmetric exchange interaction between spins on the c -axis was confirmed. However, the crystal symmetry with the space group D 4 h 18 - I 4/ m c m that had been accepted then did not allow this interaction. Thus we doubted the old crystal structure. Improving the quality of single-crystal samples, we reexamine the crystal structure of KCuF 3 by using an X-ray diffraction technique at room temperature. As a result, we confirm that F-atoms on the c -axis are displaced from the Cu-Cu bonding lines, which differs from the old structure. Consequently, a new superlattice structure is formed both along the c -axis and in the c -plane. On the basis of the newly found structure, we determine that the space group is D 2 4 - P 2 1 2 1 2 1 , and find that the local symmetry around a Cu-Cu bonding line along the c -axis allows the DM interaction with the DM vector perpendicular to the c -axis." @default.
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- W2019717364 date "1998-07-15" @default.
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- W2019717364 title "New Superlattice Crystal Structure in KCuF<sub><b>3</b></sub>Revealed by X-Ray Diffraction Experiments" @default.
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- W2019717364 doi "https://doi.org/10.1143/jpsj.67.2488" @default.
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