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• W2019747502 abstract "Chiral quinolinoxazoline ligands, a class of C1-symmetric chiral ligands, are tested in the enantioselective supported catalysis of a cyclopropanation reaction, trying to improve surface confinement effects of the clay support on the reaction stereoselectivity. In the case of trans/cis diastereoselectivity, these surface effects lead to a complete reversal of selectivity, with cis selectivity values superior to those previously found using C2-symmetryic bisoxazoline ligands. On the other hand, the enantioselectivities do not display important variations in the supported catalysts. A theoretical (DFT) mechanistic study is carried out to explain the origin of the enantioselectivity in homogeneous phase at a molecular level." @default.
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• W2019747502 date "2008-04-25" @default.
• W2019747502 modified "2023-10-03" @default.
• W2019747502 title "Surface Confinement Effects on Enantioselective Cyclopropanation. Reactions with Supported Chiral 8-Oxazolinylquinoline−Copper Complexes" @default.
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• W2019747502 doi "https://doi.org/10.1021/om7010408" @default.
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