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- W2019769055 abstract "Abstract Imido ligand transfer occurs when Os(TTP)(NC 6 H 4 NO 2 ) 2 (TTP=dianion of 5,10,15,20-tetra( p -tolyl)porphyrin) is treated with excess phosphine. The rate of transfer to PMe 3− x Ph x ( x =0, 1, 2, 3) and P(OMe) 2 Ph depends on the basicity and the steric properties of the phosphine. No imido ligand transfer is observed when Os(TTP)(NC 6 H 4 NO 2 ) 2 is treated with excess dimethyl fumarate, styrene, cis -cyclooctene, or 2,3-dimethylbutene under a variety of reaction conditions." @default.
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- W2019769055 date "2002-08-01" @default.
- W2019769055 modified "2023-09-23" @default.
- W2019769055 title "Reactivity of Os(TTP)(NC6H4NO2)2 (TTP=dianion of 5,10,15,20-tetra(p-tolyl)porphyrin) including a kinetic study of imido ligand transfer to phosphines" @default.
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