FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019773085> ?p ?o ?g. }

• W2019773085 endingPage "396" @default.
• W2019773085 startingPage "387" @default.
• W2019773085 abstract "Electron transfers (ET) of 5–hydroxy–1, 4–naphthoquinone (HNQ) and 5–hydroxy–2–methyl–1, 4–naphthoquinone (HMeNQ) have been investigated in acetonitrile and proton donors mixed media. Although there is merely a small difference in structure between HMeNQ, having a methyl, and HNQ, not having a methyl, the reduction of HNQ involves proton coupled electron transfers (PCET) process while HMeNQ not. Both CV and rapid–scan IR spectra support the existence of intermediate HNQ− and dimer in acetonitrile during electrochemical reduction. Density functional calculations show that proton transfers (PT) occur when forming dimer, indicating that HNQ has PCET–accompanied dimerization mechanism. Besides, dimer also undergoes two successive ET processes to form quinone. When proton donors are added to HNQ, dimerization is inhibited owing to intermolecular hydrogen–bonding, accompanying by the interruption of PCET process." @default.
• W2019773085 created "2016-06-24" @default.
• W2019773085 creator A5001470354 @default.
• W2019773085 creator A5075220339 @default.
• W2019773085 creator A5078198032 @default.
• W2019773085 date "2014-06-01" @default.
• W2019773085 modified "2023-09-27" @default.
• W2019773085 title "Investigation on PCET–accompanied Dimerization of 5–hydroxy–1, 4–naphthoquinone in the Process of Electrochemical Reduction by In Situ FT–IR Spectroelectrochemistry and Density Functional Calculation" @default.
• W2019773085 cites W1974035440 @default.
• W2019773085 cites W1978619070 @default.
• W2019773085 cites W1985368964 @default.
• W2019773085 cites W1992444666 @default.
• W2019773085 cites W1994858559 @default.
• W2019773085 cites W2000738543 @default.
• W2019773085 cites W2002551641 @default.
• W2019773085 cites W2007193164 @default.
• W2019773085 cites W2010592583 @default.
• W2019773085 cites W2019692171 @default.
• W2019773085 cites W2019851449 @default.
• W2019773085 cites W2021672377 @default.
• W2019773085 cites W2026735865 @default.
• W2019773085 cites W2027054748 @default.
• W2019773085 cites W2032839609 @default.
• W2019773085 cites W2047606770 @default.
• W2019773085 cites W2053249887 @default.
• W2019773085 cites W2063021902 @default.
• W2019773085 cites W2067220858 @default.
• W2019773085 cites W2070078116 @default.
• W2019773085 cites W2074618129 @default.
• W2019773085 cites W2076794403 @default.
• W2019773085 cites W2083550828 @default.
• W2019773085 cites W2084471107 @default.
• W2019773085 cites W2086595614 @default.
• W2019773085 cites W2089921133 @default.
• W2019773085 cites W2092710284 @default.
• W2019773085 cites W2092883505 @default.
• W2019773085 cites W2157794681 @default.
• W2019773085 cites W2324962753 @default.
• W2019773085 cites W2333387239 @default.
• W2019773085 doi "https://doi.org/10.1016/j.electacta.2014.03.049" @default.
• W2019773085 hasPublicationYear "2014" @default.
• W2019773085 type Work @default.
• W2019773085 sameAs 2019773085 @default.
• W2019773085 citedByCount "12" @default.
• W2019773085 countsByYear W20197730852015 @default.
• W2019773085 countsByYear W20197730852016 @default.
• W2019773085 countsByYear W20197730852017 @default.
• W2019773085 countsByYear W20197730852019 @default.
• W2019773085 countsByYear W20197730852021 @default.
• W2019773085 countsByYear W20197730852022 @default.
• W2019773085 countsByYear W20197730852023 @default.
• W2019773085 crossrefType "journal-article" @default.
• W2019773085 hasAuthorship W2019773085A5001470354 @default.
• W2019773085 hasAuthorship W2019773085A5075220339 @default.
• W2019773085 hasAuthorship W2019773085A5078198032 @default.
• W2019773085 hasConcept C110010208 @default.
• W2019773085 hasConcept C112887158 @default.
• W2019773085 hasConcept C121332964 @default.
• W2019773085 hasConcept C123669783 @default.
• W2019773085 hasConcept C147597530 @default.
• W2019773085 hasConcept C147789679 @default.
• W2019773085 hasConcept C152365726 @default.
• W2019773085 hasConcept C166950319 @default.
• W2019773085 hasConcept C17525397 @default.
• W2019773085 hasConcept C178790620 @default.
• W2019773085 hasConcept C185592680 @default.
• W2019773085 hasConcept C2776183150 @default.
• W2019773085 hasConcept C2777463227 @default.
• W2019773085 hasConcept C2779546866 @default.
• W2019773085 hasConcept C2780643102 @default.
• W2019773085 hasConcept C32909587 @default.
• W2019773085 hasConcept C52859227 @default.
• W2019773085 hasConcept C54516573 @default.
• W2019773085 hasConcept C62520636 @default.
• W2019773085 hasConcept C71240020 @default.
• W2019773085 hasConcept C75473681 @default.
• W2019773085 hasConceptScore W2019773085C110010208 @default.
• W2019773085 hasConceptScore W2019773085C112887158 @default.
• W2019773085 hasConceptScore W2019773085C121332964 @default.
• W2019773085 hasConceptScore W2019773085C123669783 @default.
• W2019773085 hasConceptScore W2019773085C147597530 @default.
• W2019773085 hasConceptScore W2019773085C147789679 @default.
• W2019773085 hasConceptScore W2019773085C152365726 @default.
• W2019773085 hasConceptScore W2019773085C166950319 @default.
• W2019773085 hasConceptScore W2019773085C17525397 @default.
• W2019773085 hasConceptScore W2019773085C178790620 @default.
• W2019773085 hasConceptScore W2019773085C185592680 @default.
• W2019773085 hasConceptScore W2019773085C2776183150 @default.
• W2019773085 hasConceptScore W2019773085C2777463227 @default.
• W2019773085 hasConceptScore W2019773085C2779546866 @default.
• W2019773085 hasConceptScore W2019773085C2780643102 @default.
• W2019773085 hasConceptScore W2019773085C32909587 @default.
• W2019773085 hasConceptScore W2019773085C52859227 @default.
• W2019773085 hasConceptScore W2019773085C54516573 @default.
• W2019773085 hasConceptScore W2019773085C62520636 @default.
• W2019773085 hasConceptScore W2019773085C71240020 @default.
• W2019773085 hasConceptScore W2019773085C75473681 @default.
• W2019773085 hasLocation W20197730851 @default.

• next