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- W2019782761 abstract "Abstract Nanoparticles of ZnFe 2 O 4, prepared by both high-energy ball milling and sol–gel methods, have been investigated by X-ray diffraction and Mossbauer spectroscopy. These results are compared with those for the bulk material. Mossbauer measurements which cover the temperature range 4.2 K to room temperature were acquired in zero field and an applied magnetic field of 5 T. The results show that the Neel temperature T N of bulk ZnFe 2 O 4 is about 9 K, whereas for the nanoparticle it is much higher; furthermore the transition temperature for particles of the same size depends on the preparation technique. The likely origin for this increase of T N in the nanoparticles, namely the redistribution of Fe and Zn cations on the A and B sites, is proposed and discussed." @default.
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- W2019782761 date "2004-01-01" @default.
- W2019782761 modified "2023-10-11" @default.
- W2019782761 title "Site preference of Fe in nanoparticles of ZnFe2O4" @default.
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- W2019782761 doi "https://doi.org/10.1016/s0304-8853(03)00544-4" @default.
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