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- W2019795943 abstract "Five and six membered ring and open chain compounds containing S-Si and S-Si-S bonds were examined by UV spectroscopy. We have found that the n-6* transition showed a blue shift as compared with the analogous carbon compounds. This fact is a consequence of the (d-p)π interaction between the lone electron pair of sulfur and the d orbitals of silicon. The results are in accordance with conclusions made on the basis of PES data. The new transition in the aromatic compounds between the α and p bands can be attributed to charge transfer interaction. The intensity of the CT band depends on the distance between sulfur and phenyl group." @default.
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- W2019795943 date "1980-01-01" @default.
- W2019795943 modified "2023-10-17" @default.
- W2019795943 title "Investigation of compounds containing si-s and s-si-s bonds by ultraviolet spectrophotometry" @default.
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- W2019795943 doi "https://doi.org/10.1016/0022-2860(80)80041-x" @default.
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