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- W2019809148 abstract "Abstract The stabilization and growth of a non‐native structure, hexagonal wurtzite MnO (h‐MnO), is explored via kinetic control of manganese precursor on a carbon sphere template. MnO is most stable in the cubic rock‐salt structure (c‐MnO), and a number of studies have focused on the synthesis and properties of this rock‐salt phase. However, h‐MnO has not been fully characterized before our work. Prolonged heating at a relatively low temperature yields c‐MnO, whereas rapid heating of the reaction mixture at reflux produces h‐MnO in the presence of carbon spheres. The effect of benzyl amine concentration on the formation of two different oxidation states (c‐MnO and t‐Mn 3 O 4 ) was examined as well. Moreover, the structural stability of the manganese oxides and phase transition of MnO in terms of the wurtzite to rock‐salt structural transformation have been investigated." @default.
- W2019809148 created "2016-06-24" @default.
- W2019809148 creator A5088776131 @default.
- W2019809148 creator A5091541638 @default.
- W2019809148 date "2014-10-09" @default.
- W2019809148 modified "2023-10-18" @default.
- W2019809148 title "Chemical Approach to a New Crystal Structure: Phase Control of Manganese Oxide on a Carbon Sphere Template" @default.
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- W2019809148 doi "https://doi.org/10.1002/asia.201403021" @default.
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