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- W2019822995 abstract "Two new singlet electronic transitions, consisting of sequences near 8400 and 9200 Å, have been recorded by Fourier transform emission spectroscopy, where the source was a microwave discharge in flowing VOCl3 vapor mixed with helium. Rotational analysis shows that these are probably 1Σ+-1Σ+ and 1Δ-1Δ transitions, and arguments are presented indicating that the carrier is VO+, for which no previous spectroscopic observations have been reported. The lower electronic states of both transitions show highly anomalous centrifugal distortion effects, presumably as a result of rotational perturbations: The perturbing electronic state may be the 3Δ state which arises from the same configuration as the lower 1Δ state." @default.
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- W2019822995 date "1984-12-01" @default.
- W2019822995 modified "2023-09-27" @default.
- W2019822995 title "Two singlet electronic transitions in the near infrared attributed to VO+" @default.
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- W2019822995 doi "https://doi.org/10.1016/0022-2852(84)90190-5" @default.
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