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- W2019856685 abstract "The extended x-ray absorption fine-structure (EXAFS) spectra of many elements and compounds have been analyzed to determine their phase functions as a function of the zero of kinetic energy, ${E}_{0}$, of the excited electron and the weighting power of the wave vector used in the Fourier transforms. It is found that a linear phase function exists for any material at some particular value of ${E}_{0}={E}_{c}$. The procedure for determining this ${E}_{c}$ value is described. A linear-phase-function method of determining bond lengths is proposed and compared to other existing methods of EXAFS bond-length determinations. The many advantages of using these linear phase functions in EXAFS analysis are discussed. With the use of the linear phase functions with a linear extrapolation of their parameters, it is demonstrated that it is possible to verify the existence of a more general form of phase transferability which relates the phase functions of different atom pairs. Such relations allow the number of phase functions needed to characterize a system of $N$ atoms to be reduced from ${N}^{2}$ to $2Nensuremath{-}1$. This type of comparison is not feasible with the usual nonlinear phase functions." @default.
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- W2019856685 date "1982-02-15" @default.
- W2019856685 modified "2023-09-23" @default.
- W2019856685 title "Determination of bond lengths from extended x-ray absorption fine structure using the linear phase functions" @default.
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- W2019856685 doi "https://doi.org/10.1103/physrevb.25.2382" @default.
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