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- W2019859493 abstract "Abstract Schiff‐base–zinc halide complexes (ZnX 2 / 1 ) thermal‐latently catalyze the reaction of glycidyl phenyl ether (2) and 1‐propoxyethyl 2‐ethylhexanoate (3) that proceeds at moderately elevated temperatures. The catalysis by the ZnX 2 / 1 complexes proceeds via the thermal dissociation of 3 to produce the corresponding carboxylic acid that nucleophilically attacks 2 predominantly over the thermally dissociated vinyl ether. ZnX 2 / 1 complexes catalyze both the dissociation of 3 to produce the carboxylic acid intermediate and its addition to 2 . Although conventional latent catalysts for this reaction exhibit Lewis acidities under ambient conditions that are responsible to the gradual degradation of hemiacetal esters and the polymerization of epoxides, a mixture of 2 , 3 , and ZnX 2 / 1 can be stored for 3 months at ambient conditions. The stored mixture is as active as the freshly prepared mixture, keeping the excellent activity and latency of ZnX 2 / 1 . As well as the model reaction, the thermally latent polyaddition of bisphenol A diglycidyl ether (9) and di‐1‐propoxyethyl adipate (10) is also promoted with ZnCl 2 / 1 at a moderate elevated temperature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3370–3379, 2007" @default.
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- W2019859493 date "2007-06-15" @default.
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- W2019859493 title "Model reaction for thermally latent curing through addition of hemiacetal ester and epoxide by schiff-base–zinc halide complexes" @default.
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- W2019859493 doi "https://doi.org/10.1002/pola.22087" @default.
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