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- W2019883170 abstract "The luminescence of the Bi3+ ion (6s2) is studied in the metaphosphates LnP3O9 (Ln = Sc, Lu, Y, Gd, La). For Ln = Sc, Lu, Y, Gd the metaphosphates have a monoclinic structure with four slightly different sites for the trivalent cations. For Ln = Sc, Lu, Y the Stokes shift of the Bi3+ luminescence increased with increasing radius of the host lattice cation. Concentration quenching of the Bi3+ luminescence is observed. In the case of GdP3O9-Bi3+ the excitation energy is transferred to the Gd3+ ions. LaP3O9 adopts an orthorhombic structure with only one site available for the trivalent cations. The different coordination of the Bi3+ ion leads to a large increase of the Stokes shift of the Bi3+ luminescence." @default.
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- W2019883170 date "1988-07-01" @default.
- W2019883170 modified "2023-10-16" @default.
- W2019883170 title "Luminescence of Bi3+ in the metaphosphates LnP3O9 (Ln = Sc, Lu, Y, Gd, La)" @default.
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- W2019883170 doi "https://doi.org/10.1016/0022-4596(88)90318-0" @default.
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