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- W2019900153 abstract "Convenient one-pot syntheses of N-substituted selenoamides (2) from nitriles, metallic selenium, carbon monoxide, water, and amines have been developed on the basis of an amino-group-exchange reaction of in situ formed N-unsubstituted selenoamides (1) with primary or secondary amines. The reactions consist of two processes, i.e., the formation of selenoamides 1 by the reaction of nitriles and H2Se formed from selenium, carbon monoxide and water, and the subsequent amino-group-exchange reaction of 1 with aliphatic amines. The obtained 2 are generally stable enough to be kept for several weeks under the atmosphere of nitrogen at 0 °C without any appreciable degradation. In the cases of primary amines, the corresponding selenoamides were also obtained from nitriles, selenium, carbon monoxide, and primary amines by a single-step mixing at the beginning of the reaction." @default.
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- W2019900153 date "1985-05-01" @default.
- W2019900153 modified "2023-10-16" @default.
- W2019900153 title "Synthesis Utilizing Reducing Ability of Carbon Monoxide. New Methods for Synthesis of<i>N</i>-Substituted Selenoamides" @default.
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- W2019900153 doi "https://doi.org/10.1246/bcsj.58.1448" @default.
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