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• W2019900181 abstract "A new blue-green emitting phosphor Ca12Al14O33Cl2:Eu2+,Mn2+ has been synthesized by the solid-state reaction technique method under a reductive atmosphere. The X-ray diffraction measurement results indicate that the crystal structure of the phosphor is a single phase of Ca12Al14O33Cl2. The phosphors can be efficiently excited by near ultraviolet (n-UV) light and show a blue emission band at about 450 nm and a green emission band at about 550 nm, which originated from the Eu2+ ions and the Mn2+ ions. The efficient energy transfer from the Eu2+ ions and the Mn2+ ions was observed and its mechanism should be a resonant type via a nonradiative dipole–quadrupole interaction. The critical distance between the Eu2+ ions and Mn2+ ions has been calculated to be about 10.83 Å as well. In addition, the temperature dependent photoluminescence of the as-prepared phosphors has been investigated in detail. Our results indicate that the developed phosphor may be used as a potential blue-green emitting phosphor for UV-based white LEDs." @default.
• W2019900181 created "2016-06-24" @default.
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• W2019900181 date "2013-01-01" @default.
• W2019900181 modified "2023-10-18" @default.
• W2019900181 title "Efficient sensitization of Mn2+ emission by Eu2+ in Ca12Al14O33Cl2 host under UV excitation" @default.
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• W2019900181 doi "https://doi.org/10.1039/c3ra41662c" @default.
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