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- W2019908976 abstract "The effect of the size of a liquid|liquid interface on the electrochemical instability (EI) has been studied voltammetrically for the transfer of decylammonium ions (DeNH3+) across the 1,2-dichloroethane|water interface formed at the tip of a micropipette. An abnormally increased irregular current (AIIC) reproducibly appears on the voltammogram without the positive feedback for the iR compensation. This fact confirms that the AIIC is not an artifact associated with the positive feedback usually employed for the iR compensation at a liquid|liquid interface of conventional size. The emergence of the AIIC at the micro liquid|liquid interface supported at the tip of the micropipette is suppressed by either a decrease in the concentration of DeNH3+ or a decrease in the diameter of the interface. The concentration of DeNH3+ required to induce the AIIC at the micro liquid|liquid interface is significantly higher than that at an interface of conventional size. The effect of the diameter of the micropipette on the AIIC is in line with the case of the aspect-ratio effect on the formation of cellular convection of the Marangoni instability." @default.
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- W2019908976 date "2007-08-13" @default.
- W2019908976 modified "2023-10-18" @default.
- W2019908976 title "Emergence of the electrochemical instability in transfer of decylammonium ion across the 1,2-dichloroethane|water interface formed at the tip of a micropipette" @default.
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