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- W2019909010 abstract "X-ray structure determination and Raman spectra of RuS2−2xSe2x and Ru1−xOsxS2 single crystals grown by the chemical vapour transport technique and tellurium fluxes respectively are presented and discussed with respect to the nature of the solid solutions, possible superstructure ordering and lattice dynamics. In the case of RuS2−2xSe2x, contrary to NiS2−2xSe2x only homonuclear S2 and Se2 units are present: these probably order, forming cobaltite-type domains. The Raman-allowed modes, which show two-mode behaviour, reflect the change in the lattice forces with increasing x. In the pyrite-type Ru1−xOsxS2, there is a random distribution of the metal ions. Both the SS bond lengths and the SS stretching modes reveal Vegard's rule-like behaviour. The S2 librations, however, are sensitive to the local environment of the S2 units in the Ru6−xOsxS2 clusters." @default.
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- W2019909010 date "1992-06-01" @default.
- W2019909010 modified "2023-10-18" @default.
- W2019909010 title "Pyrite-type RuS2−2xSe2x and Ru1−xOsxS2 solid solutions: X-ray structure determination and raman spectra" @default.
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