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- W2019910549 abstract "Numerous branch features in the (0,0) A 2Π-X 2Σ+ band system of calcium monohydride CaH have been studied by optical Stark spectroscopy. The Stark shifts, Stark splittings, and appearance of electric-field-induced transitions in the high resolution laser-induced fluorescence spectra are analyzed to produce values for the magnitude of the permanent electric dipole moments |μ| of 2.94(16) D and 2.372(12) D for the X 2Σ+(v=0) and A 2Π(v=0) states, respectively. A comparison with values predicted from a semiempirical electrostatic model and previous ab initio calculations for |μ| (X 2Σ+) is presented. The change in |μ| upon excitation from the X 2Σ+ state to the A 2Π state is rationalized using a simple molecular orbital description." @default.
- W2019910549 created "2016-06-24" @default.
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- W2019910549 date "2004-06-24" @default.
- W2019910549 modified "2023-10-18" @default.
- W2019910549 title "The permanent electric dipole moments of calcium monohydride, CaH" @default.
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- W2019910549 doi "https://doi.org/10.1063/1.1759314" @default.
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