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- W2019910825 abstract "13 C and 1 H relaxations of 13 C-enriched chloroform dissolved in the smectic A phase of S2 are measured at 90 MHz for 1 H. From various experiments for the coupled spin system together with 1 H-data for the same mol% of chloroform with natural abundance of 13 C, we have separated spectral densities on reorientation of a molecular axis of the chloroform. They are markedly different from those expected from the purely rotational dynamics; namely, only the component for fluctuation of a dipolar field in the direction of the magnetic field, which has a nonzero average in the ordered state, have been fairly large and frequency-dependent. This result is presumably due to the coupling of translational and rotational motions of the solute deeply inherent in the smectic phase." @default.
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- W2019910825 date "1995-02-15" @default.
- W2019910825 modified "2023-09-23" @default.
- W2019910825 title "Probe Dynamics of Chloroform in a Smectic Liquid Crystal. I.<sup>13</sup>C and<sup>1</sup>H NMR Relaxation" @default.
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