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• W2019913425 abstract "In the series Rh2(O2CR)4 (R = CH3, 1; R = CF3, 2), [Rh2(O2CR)2(phen)2]2+ (R = CH3, 3; R = CF3, 4), and [Rh2(O2CR)2(dppz)2]2+ (R = CH3, 5; R = CF3, 6), 2, 4, and 6 are twice as cytotoxic as 1, 3, and 5, respectively. The substitution reactions of 2 with 9-ethylguanine at various temperatures take place at faster rates than those of 1, and the activation energy Ea(1) = 69 ± 4 kJ/mol is twice Ea(2) = 35 ± 2 kJ/mol. The higher cytotoxicities of [Rh2(μ-O2CCH3)2(η1-O2CCH3)L(MeOH)]+ (L = dppz, 7; L = dppn, 8) relative to [Rh2(μ-O2CCH3)2(bpy)L]2+ (L = dppz, 10; L = dppn, 11) are attributed to the labile equatorial groups in 7 and 8 not present in 10 and 11. The toxicities of complexes 1−8 are not related to their charge or the ease by which they transverse the cellular membrane but to the lability of the ligands on the dirhodium core." @default.
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• W2019913425 date "2006-10-26" @default.
• W2019913425 modified "2023-10-18" @default.
• W2019913425 title "Dirhodium(II,II) Complexes: Molecular Characteristics that Affect in Vitro Activity" @default.
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• W2019913425 doi "https://doi.org/10.1021/jm060592h" @default.
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